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A Separating Family is a Set of Subsets in which each pair of adjacent elements are found separated,
each in one of two disjoint subsets.  The 26 letters of the alphabet can be separated by a family of 9,
See also Katona's Problem
References
Honsberger, R.  ``Cai Mao-Cheng's Solution to Katona's Problem on Families of Separating Subsets.''  Ch. 18 in 
  Mathematical Gems III.  Washington, DC: Math. Assoc. Amer., 
  pp. 224-239, 1985.
 
Sloane, N. J. A.  Sequence
A007600/M0456
in ``An On-Line Version of the Encyclopedia of Integer Sequences.''
http://www.research.att.com/~njas/sequences/eisonline.html and Sloane, N. J. A. and Plouffe, S.
The Encyclopedia of Integer Sequences.  San Diego: Academic Press, 1995.